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Chlorination of various substrates in subcritical carbon tetrachloride |
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| Authors: | Kiyoshi Tanemura Tsuneo Suzuki Takaaki Horaguchi |
| Affiliation: | a School of Life Dentistry at Niigata, Nippon Dental University, Hamaura-cho, Niigata 951-8580, Japan b Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181, Japan |
| Abstract: | Various aliphatic hydrocarbons and the side chains of aromatic hydrocarbons were chlorinated in subcritical carbon tetrachloride. Chlorination of aromatic compounds including 1,4-disubstituted benzenes was investigated. Ketones and sulfones were stable under the employed conditions. Sulfoxides were converted into sulfides in a low to modest yields. The coupling adducts between olefins and carbon tetrachloride were obtained from the reactions of olefins. |
| Keywords: | Subcritical conditions Carbon tetrachloride Chlorination Radical reactions |
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