|
|||||
|
|
Chlorination of various substrates in subcritical carbon tetrachloride |
|
| Authors: | Kiyoshi Tanemura Tsuneo Suzuki Takaaki Horaguchi |
| Institution: | a School of Life Dentistry at Niigata, Nippon Dental University, Hamaura-cho, Niigata 951-8580, Japan b Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181, Japan |
| Abstract: | Various aliphatic hydrocarbons and the side chains of aromatic hydrocarbons were chlorinated in subcritical carbon tetrachloride. Chlorination of aromatic compounds including 1,4-disubstituted benzenes was investigated. Ketones and sulfones were stable under the employed conditions. Sulfoxides were converted into sulfides in a low to modest yields. The coupling adducts between olefins and carbon tetrachloride were obtained from the reactions of olefins. |
| Keywords: | Subcritical conditions Carbon tetrachloride Chlorination Radical reactions |
| 本文献已被 ScienceDirect 等数据库收录！ | |