Ruthenium catalysts bearing chelating carboxylate ligands: application to metathesis reactions in water |
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| Authors: | Rafa? Gawin Karol Grela |
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| Institution: | a Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
b Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland |
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| Abstract: | The novel catalytic system, composed of a ruthenium alkylidene containing a surfactant fragment in the catalysts molecule, is reported. Ring closing metathesis and cross metathesis reactions proceed efficiently in neat water at room temperature, in air, without need of adding an external surfactant. |
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| Keywords: | Carbene complex Olefin metathesis Ruthenium Green chemistry Aqueous media |
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