Rh2(OAc)4 catalyzed formation of fluorine-containing polysubstituted furans from diazocompounds and aromatic alkynes |
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| Authors: | Wan Pang Shifa Zhu Yong Xin Shizheng Zhu |
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| Institution: | a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
b College of Chemistry, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | A new building block strategy for the synthesis of fluorine-containing 1,2,4-trisubstituted furan was reported. The 1,2,4-trisubstituted furan was constructed through 3+2] cycloaddition reaction of fluoroacetyl-containing diazocompound and aromatic alkyne, catalyzed by Rh2(OAc)4. |
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| Keywords: | Fluorinated diazocompounds Polysubstituted furans X-ray Crystallographic analysis |
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