Radicals in organic synthesis: part 2 |
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| Authors: | Gareth J. Rowlands [Author Vitae] |
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| Affiliation: | Institute of Fundamental Sciences—Chemistry, Massey University, Private Bag 11 222, Palmerston North, New Zealand |
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| Abstract: | |
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| Keywords: | ABCVA, 4,4&prime -azobis(4-cyanovaleric acid) (VA-501) Ac, acetyl ACCN, 1,1&prime -azobis(cyclohexanecarbonitrile) (V-40 or VAZO-88) AIBN, azobisisobutyronitrile Ar, aryl ATRA, atom transfer radical addition ATRC, atom transfer radical cyclisation ATRP, atom transfer radical polymerisation bipy, 2,2&prime -bipyridine Bn, benzyl BTAC, benzyltriethylammonium chloride Bu, butyl Bz, benzoyl CAN, cerium(IV) ammonium nitrate or ceric ammonium nitrate or diammonium cerium(IV) nitrate Cp, cyclopentadienyl CTAB, cetyltrimethylammonium bromide DCP, dicumyl peroxide DEPO, diethylphosphine oxide dHbipy, 4,4&prime -di-n-heptyl-2,2&prime -dipyridyl DLP, dilauroyl peroxide or lauroyl peroxide or dodecanoyl peroxide DMA, N,N-dimethylacetamide DMF, dimethylformamide DMP, 1,4-dimethylpiperazine DMSO, dimethylsulfoxide EDC, 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride EH, 2-ethylhexanoate EPHP, 1-ethylpiperidinium hypophosphite Et, ethyl Fmoc, 9-fluorenylmethoxycarbonyl h, hour HMPA, hexamethylphosphoramide HOBt, 1-hydroxybenzotriazole HWE, Horner-Wadsworth-Emmons IBX, 1-hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide iPr, isopropyl MAP, 4-methoxyacetophenone Me, methyl min, minute(s) MOM, methoxymethyl MS, molecular sieves MW, microwave Ph, phenyl PMB, para-methoxybenzyl PMDETA, N,N,N&prime ,N&Prime ,N&Prime -pentamethyldiethylenetriamine PMP, para-methoxyphenyl PRC, polarity-reversal catalyst/catalysis PRE, persistent-radical effect RCM, ring-closing metathesis SET, single electron transfer SEM, 2-(trimethylsilyl)methoxymethyl TBDPS, tert-butyldiphenylsilyl TBHN, di-tert-butyl hyponitrite TBHP, tert-butyl hydrogen peroxide TBPP, tert-butyl peroxypivalate TBS, tert-butyldimethylsilyl TBST, tri-tert-butoxysilanethiol TBTH, tributyltin hydride TEMPO, 2,2,6,6-tetramethylpiperidine-1-oxyl radical Tf, trifluoromethanesulfonyl or triflyl THP, tetrahydropyran TMEDA, N,N,N&prime ,N&prime -tetramethylethylenediamine TMS, trimethylsilyl Tr, trityl Ts, toluenesulfonyl or tosyl TSE, 2-tosylethyl TTMSS, tris(trimethylsilyl)silane |
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