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Preparation and properties of titania–apatite hybrid films
Affiliation:1. Department of Metallurgy and Ceramic Science, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Oookayama, Meguro-ku, Tokyo 152-8552, Japan;2. Department of Applied Biology and Chemistry, Faculty of Applied Bio-science, Tokyo University of Agriculture, 1-1-1 Sakuragaoka, Setagaya-ku, Tokyo 156-8502, Japan;3. Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan;1. Consejería de Educación, Junta de Andalucía, 41092 Sevilla, Spain;2. Instituto de Ciencia de Materiales de Sevilla, Consejo Superior de Investigaciones Científicas, Universidad de Sevilla, Avda Américo Vespucio 49, 41092 Sevilla, Spain;3. Laboratorio de rayos-X CITIUS, Avda, Reina Mercedes 4b, 41012 Sevilla, Spain;4. Unité de Catalyse et de Chimie du Solide, UCCS, CNRS, UMR 8181, Université Lille Nord de France, 59655 Villeneuve d’Ascq, France;5. Escuela de Ciencias Químicas, Universidad Pedagógica y Tecnológica de Colombia, UPTC, Avda, Central del Norte, Vía Paipa, Tunja, Boyacá, Colombia;1. School of Physics and State Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871, China;2. School of Materials Science and Engineering, Zhejiang University, Hangzhou 310058, China;1. Research Center for Gold Chemistry & Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 192-0397, Japan;1. Functional Materials Section, Materials Science and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Industrial Estate P.O., Pappanamcode, Thiruvananthapuram 695019, Kerala, India;2. T. K. M. College of Arts and Science, Kollam, Kerala, India
Abstract:TiO2–hydroxyapatite (HAp) hybrid films were prepared by laminating TiO2 films with holes on the HAp film. We prepared transparent porous HAp film through spray pyrolysis deposition (SPD) method. The HAp possessed affinity against proteins. TiO2 films were prepared using phase separation of alkoxide. The holes provided from this process serve as an adsorption field and photocatalytic reaction field for reactants. This work demonstrated that the TiO2–HAp hybrid films produced by this process are candidates for photocatalytic decomposition of germs, viruses, and other biohazardous substances in the environment.
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