| 碳纳米管修饰电极上沙丁胺醇电催化氧化研究 |
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| 引用本文： | 卫应亮,张路平,邵晨,冯辉,李现利. 碳纳米管修饰电极上沙丁胺醇电催化氧化研究[J]. 电化学, 2008, 14(3): 278. DOI: 10.61558/2993-074X.1906 |
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| 作者姓名： | 卫应亮 张路平 邵晨 冯辉 李现利 |
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| 作者单位： | 郑州轻工业学院材料与化学工程学院; |
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| 基金项目： | 河南省基础与前沿技术研究计划，郑州轻工业学院河南省表界面重点实验室资助项目 |
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| 摘 要： | 将多壁碳纳米管(MWNT)分散在疏水性表面活性剂双十六烷基磷酸(DHP)溶液中形成稳定、均相的分散液,然后制备多壁碳纳米管-DHP复合膜修饰玻碳电极(MWNT-DHP/GCE).应用方波伏安法研究了沙丁胺醇在修饰电极上的电化学行为,结果表明,碳纳米管复合膜修饰电极对沙丁胺醇的氧化有良好的电催化活性,其氧化反应为一电子一质子过程,氧化电位比裸玻碳电极负移40 mV,峰电流增加了4.5倍.在最佳测试条件下,氧化峰电流与沙丁胺醇浓度在8.3×10-7~3.3×10-6mol/L范围内呈良好线性关系,开路富集2min,检出限达1.8×10-7mol/L.该修饰电极具有良好的重现性、稳定性.
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| 关 键 词： | 碳纳米管 修饰电极 沙丁胺醇 电催化 |
| 收稿时间： | 2008-08-28 |
Study on Electrocatalytic Oxidation of Salbutamol at Carbon Nanotubes Modified Electrode |
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| WEI Ying-liang,,ZHANG Lu-ping,SHAO Chen,FENG Hui,LI Xian-li. Study on Electrocatalytic Oxidation of Salbutamol at Carbon Nanotubes Modified Electrode[J]. Electrochemistry, 2008, 14(3): 278. DOI: 10.61558/2993-074X.1906 |
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| Authors: | WEI Ying-liang ZHANG Lu-ping SHAO Chen FENG Hui LI Xian-li |
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| Affiliation: | WEI Ying-liang1,2,ZHANG Lu-ping1,SHAO Chen1,FENG Hui1,LI Xian-li1 (1.Department of Material , Chemical Engineering,Zhengzhou University of Light Industry,Zhengzhou 450002,Henan,China,2.Department of Environment Engineering , Chemistry,Luoyang Institate of Science , Technology,Luoyang 471023,China) |
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| Abstract: | The multi-wall carbon nanotubes(MWNT) were dispersed successfully into water in the presence of dihexadecyl hydrogen phosphate(DHP) and a stable well-distributed suspension.A was formed sensor based on the multi-carbon nanotubes film coated glassy carbon electrode was developed.The electrochemical response of salbutamol was studied by square wave voltammetry.The oxidation peak potential of salbutamol at the modified electrode was observed at 0.604 V,which shifted about 40 mV negatively.The peak current incr... |
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| Keywords: | carbon nanotubes modified electrode salbutamol electro-catalysis |
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