Synthesis and structural study of thiacyclophanes utilizing dibromides and methane dithiolate |
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Authors: | Rajakumar Perumal Dhanasekaran Manickam Selvam Subramaniyan Aravindan Paduthapillai Gopal Velmurugan Devadasan |
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Affiliation: | Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai, India 600 025. perumalrajakumar@hotmail.com |
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Abstract: | The synthesis of a series of thiacyclophanes and optically active binaphthol-based chiral thiacyclophanes is reported with XRD structure. Two diastereomeric tetrathiacyclophanes are designed and synthesized. The two diastereomers are evidenced by crystal structure; the single-crystal X-ray studies reveal that one of the isomers possesses an inherent property of self-assembling into a vertical stack of tunnel-like structures. |
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