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Macroporous Morphology of the Titania Films Prepared by a Sol-Gel Dip-Coating Method from the System Containing Poly(Ethylene Glycol). II. Effect of Solution Composition
Authors:Kajihara  Koichi  Yao  Takeshi
Affiliation:(1) Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan
Abstract:The influences of water and alkoxide concentrations, as well as the relative humidity upon the macroporous morphology of the titania (TiO2) films have been studied for a sol-gel dip-coating system containing poly(ethylene glycol) (PEG). The distribution of resultant morphology against the withdrawal speed and relative humidity is varied significantly by mainly modifying the polycondensation and phase separation processes during the dipping operation, even by the small change in starting composition of the dipping solution.
Keywords:macroporous titania films  phase separation  water and alkoxide concentrations  sol-gel dip-coating method
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