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Synthesis and structure of a new rhodium(I) complex [Rh{P(OPh)3}3CN] |
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| Authors: | A M Trzeciak Z Siatecki Josef J Zió?kowski |
| Institution: | (1) Institute of Chemistry, University of Wroc aw, 50-383 Wrocaw, Poland |
| Abstract: | Summary The Rh(acac){P(OPh)3)}2] complex (Hacac = 2,4-pentadione) reacts in solution with gaseous HCN in the presence of P(OPh)3 to give Rh{P(OPh)3}3CN]. Structural investigations of this complex including its31P n.m.r. spectra are reported. |
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