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Synthesis and Applications of Compartmentalised Molecular Polymer Brushes
Authors:Théophile Pelras  Dr. Clare S. Mahon  Dr. Markus Müllner
Affiliation:1. Key Centre for Polymers and Colloids, School of Chemistry, The University of Sydney, Sydney, NSW, Australia;2. The University of Sydney Nano Institute (Sydney Nano), Sydney, NSW, Australia;3. Department of Chemistry, University of York, York, UK
Abstract:Polymer science is rapidly advancing towards the precise construction of synthetic macromolecules of formidable complexity. Beyond the impressive advances in control over polymer composition and uniformity enabled by the living polymerisation revolution, the introduction of compartmentalisation within polymer architectures can elevate their functionality beyond that of their constituent parts, thus offering immense potential for the production of tailor‐made nanomaterials. In this Minireview, we discuss synthetic routes to complex molecular brushes with discrete chemical compartments and highlight their potential in the development of advanced materials with applications in nanofabrication, optics and functional materials.
Keywords:controlled polymerisation  Janus particles  molecular polymer brushes  polymer nanoparticles  self-assembly
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