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高吸油树脂的合成及对硝基苯的吸附
引用本文:周颖,刘涛,刘晓宁,徐炎华,胡俊,梁弘.高吸油树脂的合成及对硝基苯的吸附[J].南京工业大学学报(自然科学版),2011,33(2):65-69.
作者姓名:周颖  刘涛  刘晓宁  徐炎华  胡俊  梁弘
作者单位:1. 南京工业大学,环境学院,江苏,南京,210009
2. 南京工业大学,生物与制药工程学院,江苏,南京,210009
基金项目:国家高技术研究发展计划(863计划)资助项目
摘    要:采用悬浮聚合法合成了丙烯酸系高吸油性树脂。考察了树脂对硝基苯以及对模拟消防废水中硝基苯的吸附性能。研究了吸附树脂量、硝基苯初始浓度、吸附温度、离子浓度、pH等因素对均相含硝基苯的消防水吸附的影响。结果表明:吸附5 h后,对纯硝基苯的最大吸油率为30.5 g/g,吸附10 min后,对硝基苯吸油率达饱和吸油率的50%。当树脂用量为25 g/L时,硝基苯去除率达70%。树脂还具有良好的耐热及耐酸碱性,且离子浓度对吸附率无显著影响,因而能用于多种环境体系。

关 键 词:吸油性树脂  吸油率  硝基苯  消防废水

Syntheses and adsorption properties of high oil absorbing resin for nitrobenzene
ZHOU Ying,LIU Tao,LIU Xiaoning,XU Yanhua,HU Jun,LIANG Hong.Syntheses and adsorption properties of high oil absorbing resin for nitrobenzene[J].Journal of Nanjing University of Technology,2011,33(2):65-69.
Authors:ZHOU Ying  LIU Tao  LIU Xiaoning  XU Yanhua  HU Jun  LIANG Hong
Institution:1(1.College of Environment,Nanjing University of Technology,Nanjing 210009,China; 2.College of Biotechnology and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 210009,China)
Abstract:The high oil adsorption resin was synthesized by the suspension polymerization method.The adsorption performance of resin to nitrobenzene and simulating fire-fighting waste water containing nitrobenzene was investigated,and the influential factors,such as the dosage of the resin,nitrobenzene concentration,temperature,and pH on oil adsorption rate were considered.Results indicated that after adsorbing for 5 h,the maximum oil adsorption capacity was about 30.5 g/g.After 10 min,the half of the maximum oil adsorption capacity was reached.When the dosage of resin was 25 g/L,the removal ratio of nitrobenzene was 70%.In addition,the resin was resistant to heat,acid,alkali and high concentration of ions.It could be applied in multiple environments.
Keywords:oil absorption resin  absorption rate  nitrobenzene  fire-fighting water
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