| 一个含二茂铁基的镉配合物Cd(dppf)I2的合成和表征 |
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| 引用本文： | 黄尊行,王秀丽,刘世雄. 一个含二茂铁基的镉配合物Cd(dppf)I2的合成和表征[J]. 无机化学学报, 2002, 18(11): 1119-1122 |
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| 作者姓名： | 黄尊行 王秀丽 刘世雄 |
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| 作者单位： | 福州大学化学系,福州,350002 |
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| 基金项目： | 福建省教育基金资助项目(No.JA99135)，福建省高校测试基金资助，福州大学化学系基金资助。 |
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| 摘 要： | The complex containing ferroceneyl, Cd(dppf)I2(dppf=1,1-bis(diphenylphosphino) ferrocene), was syn-thesized and characterized by IR, Uv-vis DRIS spectrum and X-ray diffraction. The crystal belongs to monoclinic, space group C2/c, a=37.439(3)?, b=10.2472(6)?, c=18.719(1)?, β=110.4715(16)°, V=6727.8(8)?3, Z=8, Dc=1.818g·cm-3, F(000)=3536, μ=3.015mm-1, R=0.0308, wR=0.0692. dppf coor-dinates to Cd(Ⅱ) as bidentate ligand, and the coordination environment of Cd(Ⅱ) is a distorted tetrahedron. The electronic structures of Cd(dppf)I2 and Cd(dppf)Br2 are discussed by quantum chemistry calculation.
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| 关 键 词： | 合成 晶体结构 电子结构 二茂铁基 Cd(Ⅱ)配合物 |
| 修稿时间： | 2002-03-01 |
Synthesis and Characterization of Complex Containing Ferroceneyl Cd(dppf)I2 |
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| HUANG Zun-Xing,WANG Xiu-Li and LIU Shi-Xiong. Synthesis and Characterization of Complex Containing Ferroceneyl Cd(dppf)I2[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(11): 1119-1122 |
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| Authors: | HUANG Zun-Xing WANG Xiu-Li LIU Shi-Xiong |
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| Affiliation: | Department of Chemistry, Fuzhou University, Fuzhou 350002,Department of Chemistry, Fuzhou University, Fuzhou 350002 and Department of Chemistry, Fuzhou University, Fuzhou 350002 |
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| Abstract: | |
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| Keywords: | synthesis crystal structure electronic structure ferrocene Cd? complex |
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