| 感绿增感染料电子能级和增感性能的研究 |
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| 引用本文： | 罗世能,石俊英. 感绿增感染料电子能级和增感性能的研究[J]. 影像科学与光化学, 1986, 4(1): 8-16. DOI: 10.7517/j.issn.1674-0475.1986.01.8 |
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| 作者姓名： | 罗世能 石俊英 |
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| 作者单位： | 华东化工学院精细化工系 |
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| 摘 要： | 本文应用Hückel分子轨道理论,对一系列对称和不对称的噁碳菁、咪噁碳菁以及喹啉噻菁染料的电子能级进行了计算,测定了这些染料的激发能,极谱半波还原电位和在溴氯化银乳剂中的光谱增感性能,计算值与观测值取得了很好的一致性。
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| 收稿时间： | 1984-12-16 |
A STUDY ON THE ELECTRONIC ENERGY LEVEL AND SPECTRAL SENSITIZATION OF GREEN SENSITIZED DYES |
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| LUO SHI-NENG,SHI JUN-YINO. A STUDY ON THE ELECTRONIC ENERGY LEVEL AND SPECTRAL SENSITIZATION OF GREEN SENSITIZED DYES[J]. Imaging Science and Photochemistry, 1986, 4(1): 8-16. DOI: 10.7517/j.issn.1674-0475.1986.01.8 |
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| Authors: | LUO SHI-NENG SHI JUN-YINO |
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| Affiliation: | Department of Fine Chemical Technology, East China Institute of Chemical Technology |
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| Abstract: | In this paper the Huckel molecular orbital theory has been applied to calculate ,the electronic energy level of a series of symmetrical and unsymmetrical oxacarbocyainine, benzimidazolooxacarbocyanine and quinoline-thiacyanine dyes. Their excitation energy, polarographic half-wave potential and spectral sensitization on silver halide emulsions were measured. The agreement between the calculated and observed values is proved to be fairly good. |
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