Cyano-bridged complexes based on re tetrahedral cluster anions, Ni2+ cations, and polydentate amines |
| |
| Authors: | O A Efremova Yu V Mironov N V Kuratieva V E Fedorov |
| |
| Institution: | (1) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;(2) Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia |
| |
| Abstract: | Interaction of the tetrahedral chalcocyanide cluster anionic complexes of Re, K4Re4Q4(CN)12] (Q=S, Se, Te), with Ni2+ cationic complexes with polydentate amines, such as ethylenediamine (En), diethylenetriamine (Dien), or triethylenetetraamine (Trien) was used to synthesize six novel complexes: Ni(NH3)4(En)]{Ni(NH3)(En)2}Re4Te4(CN)12] · 2H2O, {Ni(En)2}2Re4Se4(CN)12] · 3.5H2O, Ni(NH3)3(Dien)]2Re4Se4(CN)12] · 5.5H2O, {Ni(NH3)2(Dien)}2Re4Te4(CN)12] · 2.5H2O. Ni(NH3)2(Trien)]{Ni(NH3)(Trien)}Re4Se4(CN)12] · 2.5H2O, {Ni(Trien)}2Re4S4(CN)12] · 3H2O. The complexes were studied by single-crystal X-ray diffraction analysis. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
