Alcaloides steroidiques—LII Alcaloides du buxus balearica Willd.: Cycloprotobuxine-D, buxamine-E, buxaminol-E, N-isobutyryl-baleabuxidine-F, N-benzoyl-baleabuxidine-F, baleabuxoxazine-C, N-isobutyryl-baleabuxidienine-F, N-benzoyl-baleabuxidienine-F, N-isobutyryl-baleabuxaline-F

The following alkaloides have been extracted from the leaves of Buxus balearica Willd.: cyclomicrophylline-B, cycloprotobuxines A, C and D, baleabuxine (N-isobutyryl-baleabuxine-F), buxamine-E and buxaminol-E (already reported), N-isobutyryl- and N-benzoyl-baleabuxidine-F, baleabuxoxazine-C, N-isobutyryl- and N-benzoyl-baleabuxidienine-F, N-isobutyryl-baleabuxaline-F, the structures of which are proposed. The stereochemistry of baleabuxidines and baleabuxoxazines is established on the base of chemical correlations between these two groups and cyclomicrophyllines.