Synthesis,characterization, and crystal structure of <Emphasis Type="Italic">N</Emphasis>-<Emphasis Type="Italic">p</Emphasis>-nitrobenzoyl-<Emphasis Type="Italic">N</Emphasis>′-<Emphasis Type="Italic">p</Emphasis>-chlorophenylthiourea |
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Authors: | Bi-Quan Su |
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Institution: | (1) School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China |
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Abstract: | N-p-nitrobenzoyl-N′-p-chlorophenylthiourea was synthesized and characterized by elemental analysis, IR and 1H NMR etc. Single crystal structure of the title compound was determined on X-ray diffraction instrument. It is confirmed
that the title compound crystallizes in monoclinic space group P2(1)/c, with a=8.5985(14) ?, b=12.1537(19) ?, c=14.972(2) ?, β=105.886(2)°, and D
calc=1.482 g/cm3 for Z=4. Intermolecular N–H⋯O H-bonds link pairs of two molecules. H-bonds and π-π stacking are the main non-bonding interactions
in the molecular structure. |
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Keywords: | thiourea synthesis single crystal non-bonding interaction |
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