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Effects of fullerene encapsulation on structure and photophysical properties of porphyrin-linked single-walled carbon nanotubes |
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| Authors: | Umeyama Tomokazu Mihara Junya Hayashi Hironobu Kadota Naoki Chukharev Vladimir Tkachenko Nikolai V Lemmtyinen Helge Yoshida Kaname Isoda Seiji Imahori Hirohi |
| Institution: | Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. |
| Abstract: | Fullerene-encapsulating single-walled carbon nanotubes (C(60)@SWNT) linked with porphyrins by a short bridge have been prepared for the first time. Steady state and time-resolved spectroscopies demonstrated the initial formation of an exciplex state, followed by a charge-separated state. |
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