Solvent effect on intensities off-ftransitions in lanthanide(III) complexes |
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| Authors: | Wieslaw Strek |
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| Institution: | (1) H. C. Ørsted Institute, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark;(2) Present address: Institute for Low Temperature and Structure Research, Wroclaw, Poland |
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| Abstract: | A general theory of the solvent effect on the intensities of f-f; transitions of lanthanide complexes based on static and dynamic coupling between metal ion and ligands and solvent molecules is presented. New expressions are found correlating the intensity parameters   with physical characteristics of the solvent. It is shown that the solvent effect influences only in the parameter 2. |
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| Keywords: | Lanthanide(III) complexes Solvent effect |
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