Design of ionic liquids as a medium for the Grignard reaction |
| |
| Authors: | Toshiyuki Itoh Keisuke Kude Shuichi Hayase Motoi Kawatsura |
| |
| Institution: | Department of Materials Science, Faculty of Engineering, Tottori University, 4-101 Koyama minami, Tottori 680-8552, Japan |
| |
| Abstract: | Design of novel phosphonium ionic liquids that are compatible with Grignard reagents have been investigated; several types of phosphonium salts that have an alkyl ether moiety have been synthesized and their capability evaluated as solvents for Grignard reagents. It has been established that even basic aliphatic Grignard reagent-mediated reactions are possible when methoxyethyl(tri-n-butyl)phosphonium bis(trifluoromethanesulfonyl)imide is used as the solvent. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
