Polyfluorinated phosphine ligands in the room temperature Suzuki cross-coupling reactions |
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| Authors: | Shahla Yekta |
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| Institution: | Davenport Research Laboratories, Department of Chemistry, University of Toronto 80 St. George Street, Toronto, Ontario, Canada M5S 3H6 |
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| Abstract: | Polyfluorinated phosphine ligands can be obtained by regioselective nucleophilic aromatic substitution on tetrafluoronaphthalene derivatives. The ligand efficiency has been demonstrated in the room temperature Suzuki coupling reactions of aryl bromides and aryl boronic acids. The described process allows access to a new class of highly versatile fluorinated phosphine ligands. |
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