Synthesis of Dimethyl 2-(2-Alkyl-1,3-diaryl-3-oxopropyl)malonates and Their Reactions with Amines |
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Authors: | V V Shchepin A E Korzun N Yu Poroshina |
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Institution: | (1) Perm State University, Perm, Russia |
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Abstract: | Zinc enolates generated from 1-aryl-2-bromoalkanones and zinc react with dimethyl 2-(1-arylmethylene)malonate to form dimethyl 2-(2-alkyl-1,3-diaryl-3-oxopropyl)malonates. The latter react with benzylamine or cyclohexylamine to form the corresponding disubstituted amides, while the reactions with piperidine, morpholine, and p-methoxyaniline provide monosubstituted amides of the corresponding target derivatives.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 636–641.Original Russian Text Copyright © 2005 by Shchepin, Korzun, Poroshina. |
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