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Two novel cassane diterpenoids from Acacia jacquemontii
Authors:K.C. Joshi  R.K. Bansal  T. Sharma  R.D.H. Murray  I.T. Forbes  A.F. Cameron  A. Maltz
Affiliation:Department of Chemistry, University of Rajasthan, Jaipur, India 302004;Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland
Abstract:The structure of two new diterpenoids (1 and 3), both of which contain the unique feature of a 7-membered hemiacetal ring B, have been established from chemical and spectroscopic (especially NMR) evidence. Single crystal X-ray crystallographic analysis of 1 has confirmed the structure and allowed the relative stereochemistry to be determined.
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