Two novel cassane diterpenoids from Acacia jacquemontii |
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Authors: | K.C. Joshi R.K. Bansal T. Sharma R.D.H. Murray I.T. Forbes A.F. Cameron A. Maltz |
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Affiliation: | Department of Chemistry, University of Rajasthan, Jaipur, India 302004;Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland |
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Abstract: | The structure of two new diterpenoids (1 and 3), both of which contain the unique feature of a 7-membered hemiacetal ring B, have been established from chemical and spectroscopic (especially NMR) evidence. Single crystal X-ray crystallographic analysis of 1 has confirmed the structure and allowed the relative stereochemistry to be determined. |
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