Stereoselective synthesis of the both enantiomers of disparlure,the pheromone of the gypsy moth |
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Authors: | K. Mori T. Takigawa M. Matsui |
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Affiliation: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo113, Japan |
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Abstract: | The both enantiomers of disparlure [(7R, 8S)-(+)-epoxy-2-methyloctadecane and its (7S,8R)-(?)-isomer] were synthesized from (2R, 3R)-(+)-tartaric acid in a stereoselective manner. (+)-Disparlure was found to be biologically active. |
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