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1,2-Dihydroisoquinolines—XXI: Vinylogous meerwein salts |
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| Authors: | S.F. Dyke J.F. Thorns S.H. Hedges D.W. Wiggins |
| Affiliation: | School of Chemistry, University of Bath, Bath BA2 7AY, Avon, England |
| Abstract: | Treatment of 4-acyl-1,2-dihydroisoquinolines with the Meerwein reagent (triethyloxonium tetrafluoroborate) produces vinylogues of the ethoxyimminium cations in high yield. With a view to developing syntheses of 3-substituted isoquinoline derivatives, some reactions of these salts with nucleophilic reagents have been examined. |
| Keywords: | Present address: Department of Chemistry Queensland Institute of Technology George St. Brisbane Queensland 4001 Australia. |
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