The Ru(dipy)32+-Bromate-Malonic acid oscillating system |
| |
| Authors: | E Krös L Ladányi V Friedrich Zs Nagy and Á Kis |
| |
| Institution: | (1) Institute of Inorganic and Analytical Chemistry, L. Eötvös University, Budapest, Hungary |
| |
| Abstract: | The Ru(dipy)
3
2+
-bromate-malonic acid oscillating system was in vestigated. It has been established that at early stages of the reaction the period of oscillation is about 20 sec and the potential change is about 170 mV; chloride at concentrations hiherg than 10–3M is an inhibitor. The rates of both heat evolution and formation of bromomalonic acid are periodic. The  activation energy of the oscillating (E ) is 16.2 kcal mol–1.                   Ru(dipy)
3
2+
- -  .   ,    20 , 170 ;  , -  10–3 M,  .    .  (E) 16,2 /. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
