Mössbauer study of the effect of preparation parameters in rapidly quenched Fe−Cr−P−C,Fe−Cr−B and Ni(57Fe)P amorphous alloys

Mössbauer spectroscopy was used to get information about the effect of preparation parameters (quenching rate, temperature and time of solution treatment of melt) on the structure of rapidly quenched Fe₇₀Cr₁₀C₇P₁₃, Fe₇₉Cr₁₅B₁₅ and Ni₈₀ ⁵⁷Fe₁P₁₉ amorphous alloys. We have found smaller but measurable thickness dependent changes in the average Mössbauer parameters and in the hyperfine field distribution of Fe₇₀Cr₁₀C₇P₁₃ samples than those observed in Fe₇₀Cr₁₀C₁₀P₁₀ amorphous alloys [3]. On the other hand, differences were found in the hyperfine field distribution of very rapidly quenched Fe₇₀Cr₁₀C₇P₁₃ alloys with increasing time of solution treatment of melt. Changes in the average parameters and in the quadrupole splitting distribution were also observed with variation of thickness as well as of temperature of melt in the Fe₇₀Cr₁₅B₁₅ and Ni₈₀(Fe)P₁₉ samples, respectively. The finding can be interpreted in terms of changes in the short range order due to different preparation conditions.