Precipitation from homogeneous solution of cations released from ETDA complexes |
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Authors: | Grzeskowiak R Turner T A |
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Institution: | Department of Chemistry, Woolwich Polytechnic, London S.E.18, U.K. |
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Abstract: | The suitability of EDTA complexes for use in precipitation of certain cations from homogeneous solution under various experimental conditions can be predicted from a knowledge of the solubility product of the compound to be precipitated and the complex stability constant. A brief review of previous work in the field of masking effectiveness is given. An examination of factors influencing precipitation has been carried out. It is shown that a simple ratio can be used for predicting the likelihood of precipitation at various pH values and that more rigorous theoretical approaches are not necessarily more advantageous. |
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