| 11-钨锌三元杂多阴离子层状化合物的合成、表征及催化活性 |
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| 引用本文： | 单秋杰.11-钨锌三元杂多阴离子层状化合物的合成、表征及催化活性[J].光谱实验室,2011,28(5):2351-2356. |
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| 作者姓名： | 单秋杰 |
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| 作者单位： | 齐齐哈尔大学化学与化工学院 黑龙江省齐齐哈尔市文化大街42号161006 |
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| 摘 要： | 用离子交换法将具有K egg in结构11-钨锌三元杂多化合物K8M ZnW11（H2O）O39]（M=Co2＋、N i2＋、Cu2＋、Cd2＋）嵌入到Zn2A l类水滑石中,得到层状化合物：Zn2A l-M ZnW11（H2O）O39]（M=Co2＋、N i2＋、Cu2＋、Cd2＋）,并用XRD、IR、UV对其进行了表征。结果表明,杂多阴离子进入水滑石层间后,仍保留了其K egg in结构。利用层状化合物催化合成乙酸正丁酯考察其催化活性,结果表明,层状化合物在酯化反应中显示优良的催化性能。
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| 关 键 词： | 三元杂多阴离子 层状化合物 Keggin结构 酯化反应 |
Synthesis,Characterization and Catalytic Activity of 11-Tungstozincic Ternary Heteropoly-Anion Layered Compounds |
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| SHAN Qiu-Jie.Synthesis,Characterization and Catalytic Activity of 11-Tungstozincic Ternary Heteropoly-Anion Layered Compounds[J].Chinese Journal of Spectroscopy Laboratory,2011,28(5):2351-2356. |
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| Authors: | SHAN Qiu-Jie |
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| Institution: | SHAN Qiu-Jie(School of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar,Heilongjiang 161006,P.R.China) |
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| Abstract: | Zn2Al-MZnW11(H2O)O39](M=Co2+,Ni2+,Cu2+,Cd2+)were synthesized by ion-exchange method for insetion of 11-tungstozincic ternary heteropoly-anion layered compounds with Keggin structure into Zn2Al hydrotalcite,and were characterized by XRD,IR and UV.After the heteropoly-anions insetting layered of hydrotalcite,the layered compounds were still Keggin structure.The n-Butyl acetate was synthesized with the catalyst of layered compounds.The results indicated that the layered compounds had good catalytic activity o... |
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| Keywords: | Ternary Heteropoly-Anion Layered Compound Keggin Structure Esterification Reaction |
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