| 氢氧化铁共沉淀-氢化物发生-原子荧光光谱法测定卤水中痕量硒 |
| |
| 引用本文： | 仲金虎,王培艳,肖玉萍. 氢氧化铁共沉淀-氢化物发生-原子荧光光谱法测定卤水中痕量硒[J]. 光谱实验室, 2011, 28(6): 3207-3209 |
| |
| 作者姓名： | 仲金虎 王培艳 肖玉萍 |
| |
| 作者单位： | 青海省柴达木综合地质矿产勘查院测试中心 青海省格尔木市昆仑南路12号816000 |
| |
| 摘 要： | 氢氧化铁共沉淀分离卤水中痕量硒,用盐酸溶解沉淀并酸化,盐酸水浴加热还原六价硒为四价硒,氢化物发生-原子荧光光谱法测定硒.检出限( 3S/N)为=0.076μg·mL-1,加标回收率为90.0％-100.0％,相对标准偏差(n=11)为1.25％.
|
| 关 键 词： | 共沉淀 卤水 氢化物发生-原子荧光光谱法 硒 |
Determination of Trace Selenium in Brine by Hydride Generation-Atomic Fluorescence Spectrometry with Ferric Hydroxide Co-precipitation |
| |
| ZHONG Jin-Hu,WANG Pei-Yan,XIAO Yu-Ping. Determination of Trace Selenium in Brine by Hydride Generation-Atomic Fluorescence Spectrometry with Ferric Hydroxide Co-precipitation[J]. Chinese Journal of Spectroscopy Laboratory, 2011, 28(6): 3207-3209 |
| |
| Authors: | ZHONG Jin-Hu WANG Pei-Yan XIAO Yu-Ping |
| |
| Affiliation: | ZHONG Jin-Hu WANG Pei-Yan XIAO Yu-Ping(Qinghai Province Comprehensive Geological Mineral Courtyard Chaidamu Test Center,Geermu,Qinghai 816000,P.R.China) |
| |
| Abstract: | Trace selenium in brine was separated by ferric hydroxide co-precipitation,and the co-precipitation was dissolved and acidized by hydrochloric acid,and Se（Ⅵ） was reduced to Se（Ⅳ） in heating water bath of hydrochloric acid,then the selenium was determined by hydride generation-atomic fluorescence spectrometry（HG-AFS） after separation.The instrument detection limit was 0.076μg·mL-1.The recoveries of the method was 90.0%—100.0%.The precision（RSD,n=11） was 1.25%. |
| |
| Keywords: | Co-precipitation Brine HG-AFS Selenium |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
