| 生化废水COD的近红外光谱法测定 |
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| 引用本文： | 粟晖,姚志湘,黎国梁,兰月来.生化废水COD的近红外光谱法测定[J].光谱实验室,2011,28(6):3040-3043. |
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| 作者姓名： | 粟晖 姚志湘 黎国梁 兰月来 |
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| 作者单位： | 1. 广西工学院生物与化学工程系 广西柳州市城中区东环大道268号545006
2. 广西工学院生物与化学工程系 广西柳州市城中区东环大道268号545006;广西大学化学化工学院 南宁市530004 |
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| 基金项目： | 广西自然科学基金资助项目(桂科自0832064); 广西教育厅桂教科研资助项目(200708MS067) |
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| 摘 要： | 采用近红外光谱测定在紫外光谱区表现为弱吸收响应的生化废水的化学需氧量（COD）。通过主成分分析-欧氏空间距离类聚法筛选出具有代表性的样本,从系统独立变量数的角度判断了主成分数,结合变量标准化-基线扣除的预处理方法消除光谱信号背景干扰,建立了偏最小二乘校正模型。在系统主成分数为6时,水样的COD实测值与预测值之间的相关系数为0.9348,预测标准差（RM SEC）为61.89m g/L,模型有较好的预测能力。
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| 关 键 词： | 化学需氧量 近红外光谱 偏最小二乘法 |
Determination of COD in Biological and Chemical Wastewater by Near Infrared Spectrometry |
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| SU Hui,YAO Zhi-Xiang,LI Guo-Liang,LAN Yue-Lai.Determination of COD in Biological and Chemical Wastewater by Near Infrared Spectrometry[J].Chinese Journal of Spectroscopy Laboratory,2011,28(6):3040-3043. |
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| Authors: | SU Hui YAO Zhi-Xiang LI Guo-Liang LAN Yue-Lai |
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| Institution: | SU Huia YAO Zhi-Xianga LI Guo-Lianga,b LAN Yue-Laiaa(Department of Biology and Chemical Engineering,Guangxi University of Technology,Liuzhou,Guangxi 545006,P.R.China)b(College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,P.R.China) |
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| Abstract: | The COD in biological and chemical wastewater that performed to weak absorption in the UV spectral region was determined by NIR spectrometry.Principal component analysis-Euclidean distance cluster was applied to select the representative sample.From the aspect of the number of independent variables,the number of principal components was determined.Combined with the SNV-Detrending preprocessing,the background signal of spectra was eliminated.The partial least squares model was built and the predictions were ... |
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| Keywords: | Chemical Oxygen Demand Near-Infrared Spectrometry PLS |
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