| NMP与ROP相结合制备PCL-b-PSt共聚物及其性能研究 |
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| 引用本文： | 李翠珍,刘建静,张琰,郎美东. NMP与ROP相结合制备PCL-b-PSt共聚物及其性能研究[J]. 功能高分子学报, 2011, 24(3): 225-230 |
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| 作者姓名： | 李翠珍 刘建静 张琰 郎美东 |
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| 作者单位： | 东华理工大学材料系,江西抚州,344000 |
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| 基金项目： | 中央高校基本科研业务费(WD0913008,WD1014036); 国家自然科学基金资助项目(20804015) |
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| 摘 要： | 以4-羟基-2,2,6,6-四甲基哌啶氮氧自由基（HTEMPO）为引发剂,通过ε-己内酯（ε-CL）的开环聚合,合成末端基为氮氧自由基的聚己内酯（PCL-T）。在其调控下,进行过氧化苯甲酰（BPO）引发苯乙烯（St）的自由基聚合,合成结构规整的聚己内酯-b-聚苯乙烯（PCL-b-PSt）共聚物。用氢核磁共振（1H-NM...
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| 关 键 词： | 氮氧稳定自由基聚合 开环聚合 聚苯乙烯 聚己内酯 |
Synthesis and Properties of PCL-b-PSt Copolymer Prepared from the Combination of Nitroxide-Mediated Radical Polymerization and Ring-Opening Polymerization |
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| LI Cui-zhen,,LIU Jian-jing,ZHANG Yan,LANG Mei-dong. Synthesis and Properties of PCL-b-PSt Copolymer Prepared from the Combination of Nitroxide-Mediated Radical Polymerization and Ring-Opening Polymerization[J]. Journal of Functional Polymers, 2011, 24(3): 225-230 |
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| Authors: | LI Cui-zhen LIU Jian-jing ZHANG Yan LANG Mei-dong |
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| Affiliation: | LI Cui-zhen1,2,LIU Jian-jing1,ZHANG Yan1,LANG Mei-dong1(1.Key Laboratory for Ultrafine Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China,2.Department of Materials,East China Institute of Technology,Fuzhou 344000,Jiangxi,China) |
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| Abstract: | |
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| Keywords: | nitroxide-mediated radical polymerization ring-opening polymerization polystyrene polycaprolactone |
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