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黄芩有效成分的紫外-可见吸收光谱表征
引用本文:李云霞,索全伶,贺文智,李春萍,黄延春.黄芩有效成分的紫外-可见吸收光谱表征[J].光谱学与光谱分析,2007,27(1):131-134.
作者姓名:李云霞  索全伶  贺文智  李春萍  黄延春
作者单位:内蒙古师范大学化学与环境科学学院,内蒙古,呼和浩特,010022;内蒙古工业大学化工学院,内蒙古呼,和浩特,010051
基金项目:国家自然科学基金 , 内蒙古高等学校科研项目
摘    要:利用紫外-可见光谱的方法,对从中药黄芩中分离得到的3种黄芩有效成分的分子结构进行了研究。通过分析黄芩有效成分在甲醇溶液中及分别加入甲醇钠(NaOMe)、醋酸钠(NaOAc)、醋酸钠/硼酸(NaOAc/H3BO3)等5种诊断试剂后的紫外-可见光谱特征,讨论了利用紫外-可见吸收光谱推断黄酮类化合物母核结构及取代基位置的方法,为天然产物有效成分的结构鉴定提供了参考依据。

关 键 词:黄芩  有效成分  紫外-可见光谱  结构鉴定
文章编号:1000-0593(2007)01-0131-04
收稿时间:2005-12-08
修稿时间:2006-03-26

UV-Vis Spectroscopic Characterization of Active Components from Scutellaria Baicalensis Georgi
LI Yun-xia,SUO Quan-ling,HE Wen-zhi,LI Chun-ping,HUANG Yan-chun.UV-Vis Spectroscopic Characterization of Active Components from Scutellaria Baicalensis Georgi[J].Spectroscopy and Spectral Analysis,2007,27(1):131-134.
Authors:LI Yun-xia  SUO Quan-ling  HE Wen-zhi  LI Chun-ping  HUANG Yan-chun
Institution:1. Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China2. Chemical and Environmental Science College, Inner Mongolia Normal University, Hohhot 010022, China
Abstract:The molecular structures of three active components from scutdlaria baicalensis have been studied by ultraviolet-visible spectra. The index flavonoid structures and substituted positions were deduced by analyzing the UV-Vis spectra in the methanol solution of three active components and the methanol solution with 5 diagnostic reagents, NaOMe, NaOAc, NaOAc/H3BO3, AlCh, AlCh/HCl respectively, which provided strong evidences for the structural characterization of the active components from natural products.
Keywords:Scutellaria baicalensis Georgi  Active component  UV-Vis spectrum  Structure characterization
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