Synthesis, photophysical properties and TD-DFT calculation of four two-photon absorbing triphenylamine derivatives |
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Authors: | Lin Kong JiaXiang Yang HongPing Zhou ShengLi Li FuYing Hao Qiong Zhang YuLong Tu JieYing Wu ZhaoMing Xue YuPeng Tian |
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Affiliation: | 1. Department of Chemistry, Key Laboratory of Functional Inorganic Materials of Anhui Province, Anhui University, Hefei, 230039, China 2. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China 3. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China
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Abstract: | In this study, linear absorption, single-photon excited fluorescence, fluorescence quantum yields, fluorescence lifetime and two-photon excited fluorescence of a series of triphenylamine derivatives (L1, L2, L3 and L4) have been measured. L1 and L3 are D-π-A type dyes, while L2 and L4 are D-π-D-π-A type dyes (D = donor, A = acceptor). The investigated compounds consist of triphenylamine-bearing donor-substituted and/or systematically extended π-conjugated length, which are designed to gain insight into the effect of the ethoxyl unit and π-linkage length on the linear and nonlinear optical properties. The influence of solvent polarity on the photophysical properties was investigated. Employing time-dependent density functional theory (TD-DFT) calculations, the structure-property relationships are discussed. |
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