Molecular complexation and binding studied by electrophoretic NMR spectroscopy |
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Authors: | Hallberg Fredrik Weise Christoph F Yushmanov Pavel V Pettersson Erik Thyboll Stilbs Peter Furó István |
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Affiliation: | Division of Physical Chemistry, Department of Chemistry, Royal Institute of Technology, SE-10044 Stockholm, Sweden. |
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Abstract: | Electrophoretic mobilities obtained on a molecularly selective manner by electrophoretic NMR can be used to provide a quantitative characterization of the composition and stoichiometry of molecular complexes. This is demonstrated in complexes formed by uncharged cyclodextrins which attain an electrophoretic mobility upon inclusion of charged surfactants. |
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