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Molecular complexation and binding studied by electrophoretic NMR spectroscopy
Authors:Hallberg Fredrik  Weise Christoph F  Yushmanov Pavel V  Pettersson Erik Thyboll  Stilbs Peter  Furó István
Institution:Division of Physical Chemistry, Department of Chemistry, Royal Institute of Technology, SE-10044 Stockholm, Sweden.
Abstract:Electrophoretic mobilities obtained on a molecularly selective manner by electrophoretic NMR can be used to provide a quantitative characterization of the composition and stoichiometry of molecular complexes. This is demonstrated in complexes formed by uncharged cyclodextrins which attain an electrophoretic mobility upon inclusion of charged surfactants.
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