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Chemistry and Structure of Diterpene Compounds of the Kaurane Series: VIII. Azomethines Derived from Isosteviol
Authors:Al'fonsov  V. A.  Andreeva  O. V.  Bakaleinik  G. A.  Beskrovnyi  D. V.  Gubaidullin  A. T.  Kataev  V. E.  Kovylyaeva  G. I.  Konovalov  A. I.  Korochkina  M. G.  Litvinov  I. A.  Militsina  O. I.  Strobykina  I. Yu.
Affiliation:(1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia
Abstract:(4agr,8beta,13beta)-13-Methyl-16-oxo-17-norkaurane-18-carboxylic acid (isosteviol) and its methyl ester were reacted with benzylamine and hydroxylamine to obtain the corresponding E-stereoisomeric 16-ketimines. Isosteviol benzylimine and oxime form individual 1:1 H-bonded complexes with methanol and water, respectively.
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