Synergistic extraction of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate and 1,2-(diphenylphosphino)ethane dioxide |
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| Authors: | E Makrlík P Vaňura P Selucky and Z Spíchal |
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| Institution: | (1) Faculty of Applied Sciences, University of West Bohemia, Husova 11, 306 14 Pilsen, Czech Republic;(2) Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technick? 5, 166 28 Prague 6, Czech Republic;(3) Nuclear Research Institute, 250 68 Řež, Czech Republic;(4) Department of Inorganic Chemistry, Faculty of Science, Masaryk University, Kotl?řsk? 2, 611 37 Brno, Czech Republic |
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| Abstract: | Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of 1,2-(diphenylphosphino)ethane dioxide (DPPEtDO, L) has been investigated. The equilibrium data have been
explained assuming that the species HL+, HL2
+, ML2
3+ and ML4
3+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated
with water have been determined. It was found that the stability constants of the corresponding complexes EuL
n
3+ and AmL
n
3+, where n = 2, 4 and L is DPPEtDO, in water-saturated nitrobenzene are comparable. |
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| Keywords: | |
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