Electrochemical studies of determination of C.I. Direct Red 80 based on a gold nanoparticles-modified carbon paste electrode |
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Authors: | Sayed Mehdi Ghoreishi Mohsen Behpour Mahshid Golestaneh |
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Institution: | 1. Department of Analytical Chemistry , Faculty of Chemistry, University of Kashan , Kashan , I. R. Iran s.m.ghoreishi@kashanu.ac.ir;3. Department of Analytical Chemistry , Faculty of Chemistry, University of Kashan , Kashan , I. R. Iran |
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Abstract: | In this paper, a simple, convenient and sensitive electrochemical method has been developed for the determination of C.I. Direct Red 80. A gold nanoparticle modified carbon paste electrode was fabricated and used for study and sensitive determination of Direct Red 80 by cyclic voltammetry and differential pulse voltammetry. The overall analysis involved a two-step procedure: an accumulation step under open-circuit conditions, followed by voltammetric measurements of Direct Red 80 in a 0.1?M phosphate buffer solution at pH?=?3.0. The experimental conditions, such as the medium, pH and accumulation time, were optimised. The oxidation peak current was proportional to the concentration of Direct Red 80 from 5.0?×?10?8 to 5.0?×?10?7?M and 5.0?×?10?7 to 3.0?×?10?6?M, and the detection limit was 1.15?×?10?8?M (S/N?=?3). The proposed method was used to detect Direct Red 80 in natural water and sewage with good accuracy. |
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Keywords: | Direct Red 80 gold nanoparticles carbon paste electrode voltammetry determination |
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