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Influence of the rare earth element substitution on oxygen adsorption-desorption properties of YBCO
Authors:Fan Yu-shan  Song Hong-zhang  Li Zhi-hui  Yang De-lin and Hu Xing
Institution:(1) School of Physics Engineering and Key Laboratory of Materials Physics of Ministry of Education of China, Zhengzhou University, Zhengzhou, 450052, China
Abstract:The oxygen adsorption-desorption properties of RBa2Cu3O7−δ (R = Gd, Er, Eu, Dy, Sm, Ho and Nd) and Y1−x LaxBa2Cu3O7−δ (x=0.1, 0.5 and 1.0) were investigated from room temperature to 950 °C by thermogravimetry (TG). The results show that all samples will release oxygen with the increasing of temperature and the released oxygen can be absorbed back into the sample when temperature decreases. However, dependent on the rare earth element, the amount of the released oxygen is different for these samples. Moreover, in the temperature increasing and decreasing circle the repetition of oxygen adsorption-desorption is also different.
Keywords:YBa2Cu3O7−  δ                          rare earth  substitution  oxygen adsorption-desorption  thermogravimetry
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