Control of molecular architecture by steric and electronic factors: dinuclear side-by-side vs. tetranuclear [2 x 2] grid-type silver(I) complexes |
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Authors: | Price Jason R Lan Yanhua Jameson Geoffrey B Brooker Sally |
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Institution: | Department of Chemistry, University of Otago, P.O. Box 56, Dunedin, New Zealand. |
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Abstract: | Silver(I) complexes of the two closely related linear bis-bidentate pyridazine-based Schiff-base ligands 5 and 6 exhibit very different solid state molecular architectures, easily deformed grid vs. side-by-side, due to steric and electronic factors. |
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