The gas-phase molecular structure of 1-fluorosilatrane from electron diffraction |
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Authors: | György Forgács Mária Kolonits István Hargittai |
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Institution: | (1) Structural Chemistry Research Group of the Hungarian Academy of Sciences, Eötvös University, Pf. 117, H-1431 Budapest, Hungary |
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Abstract: | The molecular geometry of 1-fluorosilatrane has been determined by gas-phase electron diffraction. The distance between the nitrogen and silicon atoms is much longer in the gas phase, viz., 2.324±0.014 Å, than in the crystal, 2.042 (1) Å 5]. This indicates a weakened donor-acceptor interaction possibly as a consequence of the absence of intermolecular interactions in the gas phase. The five-membered rings take envelope conformations with the carbon atoms adjacent to nitrogen at the envelope tips. The following bond distances (
g
, Å) and bond angles (°) were obtained with their estimated total errors: N-C, 1.481±0.008; C-C, 1.514±0.011; O-C, 1.392±0.004; Si-O, 1.652±0.003; Si-F, 1.568±0.006; C-H, 1.118±0.005; N-C-C, 104.5±0.6; C-C-O, 117.0±0.7;C-O-Si, 123.7±0.6; O-Si-F, 98.7±0.3; O-Si-O, 117.8±0.1; C-N-C, 115.0±0.3. |
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