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Thieno[3,2-b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices
Authors:Bronstein Hugo  Chen Zhuoying  Ashraf Raja Shahid  Zhang Weimin  Du Junping  Durrant James R  Tuladhar Pabitra Shakya  Song Kigook  Watkins Scott E  Geerts Yves  Wienk Martijn M  Janssen Rene A J  Anthopoulos Thomas  Sirringhaus Henning  Heeney Martin  McCulloch Iain
Institution:Imperial College London, London SW7 2AZ, UK. h.bronstein@imperial.ac.uk
Abstract:We report the synthesis and polymerization of a novel thieno3,2-b]thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm(2) V(-1) s(-1), which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC(71)BM gave a power conversion efficiency of 5.4%.
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