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Asymmetric synthesis of tertiary and quaternary allyl- and crotylsilanes via the borylation of lithiated carbamates |
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| Authors: | Aggarwal Varinder K Binanzer Michael de Ceglie M Carolina Gallanti Maddalena Glasspoole Ben W Kendrick Stephanie J F Sonawane Ravindra P Vázquez-Romero Ana Webster Matthew P |
| Institution: | School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK. v.aggarwal@bristol.ac.uk |
| Abstract: | Tertiary allyl- or crotylsilanes have been prepared in high er and dr via the lithiation-borylation reaction of alkyl carbamates with silaboronates. Using a related strategy, quaternary allylsilanes could be accessed in similarly high er. |
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