Open-Framework Rubidium Halides Incorporated in Cadmium Oxalate Host Lattices |
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Authors: | R VaidhyanathanSrinivasan Natarajan CNR Rao |
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Institution: | Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore, 560 064, India |
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Abstract: | The metathetic reaction between CdBr2 and rubidium oxalate under hydrothermal conditions yields RbBr] Cd6(C2O4)6]·2H2O, I, containing Cd6O24 clusters with the Br− ions in the center. The RbBr moiety forms a three-dimensional Fm3m structure, but with a unit cell double that of the normal stable phase. The hydrothermal reaction between rubidium oxalate and CdCl2 in the presence of NO−3 ions gives Rb2Cd(NO3)(Cl)(C2O4)(H2O)], II, containing cadmium chloro-oxalate layers. The Rb+ ions present between the layers interact with the Cl atoms to form a one-dimensional RbCl chain decorated by NO−3 groups. |
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