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Room Temperature Solid State Reaction Involving Structural Transformation of Covalent Oxide Network
Authors:Kazuo EdaSatoshi Fukiharu  Takashi SuzukiNoriyuki Sotani
Affiliation:Department of Chemistry, Faculty of Science, Kobe University, Nada-ku, Kobe, 657-8501, Japanf1eda@kobe-u.ac.jpf1
Abstract:An interesting structural transformation from a two dimensional (2d) covalent oxide network with a layered structure to a three-dimensional (3d) network with a tunnel structure was found at room temperature in the mixture of hydrated alkali-metal molybdenum bronze and amorphous alkali-metal molybdate. From various experimental results it was concluded that the transformation was due to a room temperature solid state reaction.
Keywords:solid state reaction   room temperature reaction   transformation of covalent oxide network   Mo-O system.
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