Thermal stability of phosphine and phosphine oxide complexes of cobalt(ii) dihalides |
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Authors: | K. Moedritzer R. E. Miller |
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Affiliation: | (1) Central Research Department, Monsanto Company, St. Louis, Missouri, USA |
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Abstract: | Thermogravimetric measurements show that complexes of cobalt(II) dihalides with aryl and alkyl substituted phosphines and triphenylphosphine oxide in an oxygen containing atmosphere decompose to yield solid phases consisting of Co3O4 and P2O5.
Zusammenfassung Komplexe von Kobalt(II)dihalogeniden mit aryl- und alkylsubstituierten Phosphinen und Triphenylphosphinoxyd wurden einer thermogravimetrischer Prüfung unter Sauerstoff unterworfen. Die zurückbleibende feste Phase bestand aus Co3O4 und P2O5.
Résumé On a étudié la décomposition thermique des complexes dihalogénés de cobalt(II) avec les aryl et alcoylphosphines substituées et les oxydes de triphénylphosphine. En atmosphère d'oxygène, Co3O4 et P2O5 constituent la phase solide résiduelle.
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