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Nitrate ion-sensitive field effect transistor based on bis(bathocuproin)-copper(I) nitrate dissolved in solid solvents
Authors:Hirokazu Hara   Kazunori Takahashi  Hiromi Ohkubo
Affiliation:

Department of Chemistry, Faculty of Education, Shiga University, Otsu, Shiga 520, Japan

Abstract:Nitrate-selective ion-sensitive field effect transistors (ISFETs) were prepared by dip-coating the silica gate insulator surface with an ion exchanger based on bis(bathocuproin)-copper(I) nitrate in a molten mixture of docosan 1-ol and Triphenylphosphate. This sensor showed a linear response from 10−1 mol dm−3 to at least 10−5 mol dm−3 and maintained its response characteristics for as long as 5 weeks. The selectivity sequence for common anions such as Cl0−4 and Cl− followed the conventional Hofmeister series. This sensor was applied to rain water analysis.
Keywords:Ion exchange   Sensors   Ion-sensitive field transistors   ISFET   Nitrate   Membrane electrodes   Rain water   Waters
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