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Shape-persistent arylenevinylene macrocycles (AVMs) prepared via acyclic diene metathesis macrocyclization (ADMAC)
Authors:Jin Yinghua  Zhang Aibo  Huang Yongshun  Zhang Wei
Affiliation:Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA.
Abstract:Shape-persistent arylenevinylene macrocycles (AVMs) were successfully prepared in one step from readily available aromatic diene monomers through olefin metathesis in good yields. (1)H NMR, UV-Vis absorption and fluorescence studies revealed the aggregation behavior of the obtained macrocycles. SEM characterization showed AVM nanofibril formation.
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