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Enhanced interfacial adhesion,mechanical, and thermal properties of natural flour-filled biodegradable polymer bio-composites
Authors:Hee-Soo Kim  Byoung-Ho Lee  Sena Lee  Hyun-Joong Kim  John R Dorgan
Institution:(1) Research and Development Institute, Research 2 Team, Woongjin Chemical Co., Ltd, Suwon, 443-270, Republic of Korea;(2) Laboratory of Adhesion and Bio-Composites, Program in Environmental Materials Science, Seoul National University, Seoul, 151-921, Republic of Korea;(3) Research Institute for Agriculture and Life Sciences, Seoul National University, Seoul, 151-921, Republic of Korea;(4) Colorado Center for Biorefining and Biofuels, Department of Chemical and Biochemical Engineering, Colorado School of Mines, Golden, CO 80401-1887, USA;
Abstract:This study examined the interfacial adhesion, mechanical, and thermal properties of compatibilizing agent-treated and non-treated biocomposites as a function of the type of compatibilizing agent. The tensile strength, interfacial adhesion, and heat deflection temperature (HDT) of maleic anhydride-grafted poly(butylene succinate) (PBS-MA) and maleic anhydride-grafted poly(lactic acid) (PLA-MA)-treated biocomposites are greater than those of untreated maleic anhydride-grafted poly(styrene-b-ethylene-co-butylene-b-styrene) triblock copolymer (SEBS-MA) and maleic anhydride-grafted polypropylene (MAPP)-treated biocomposites. The storage modulus (E′) values and the tan δmax temperatures (T g) of PBS-MA and PLA-MA-treated biocomposites were slightly higher than that of the untreated biocomposites.
Keywords:
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